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Polychlorotrifluoroethylene (PCTFE) Engineered Plastics

Polychlorotrifluoroethylene (PCTFE)

PCTFE is a high-performance fluoropolymer known for its exceptionally low moisture absorption, superior dimensional stability, and excellent chemical resistance. Compared to PTFE, PCTFE offers significantly higher stiffness and strength while retaining many of the desirable characteristics of fluoropolymers.

This balance of mechanical integrity and environmental resistance makes PCTFE a preferred material for precision components that must maintain tight tolerance in the presence of chemicals, pressure, or cryogenic conditions. It is widely used where permeability control, moisture resistance, and long-term reliability are critical.

PCTFE Properties Overview

PCTFE distinguishes itself among fluoropolymers by combining low permeability and moisture resistance with improved mechanical performance. While it does not match PTFE’s frictional properties, PCTFE excels in applications requiring dimensional accuracy and barrier performance under demanding service conditions.

  • Temperature Performance
    • Continuous operating temperature ranges from -400 °F (-240 °C) to 380 °F (193 °C)
    • Maintains toughness and dimensional stability at cryogenic temperatures
  • Chemical Resistance
    • Excellent resistance to most acids, bases, solvents, fuels, and process chemicals
    • Lower chemical permeability compared to PTFE, making it suitable for containment and sealing applications
    • Resistant to hydrocarbon-based fluids and aggressive media
  • Moisture & Gas Barrier Properties
    • Extremely low moisture absorption among thermoplastics
    • Outstanding resistance to gas permeation
  • Mechanical Characteristics
    • Higher tensile strength, stiffness, and hardness than PTFE
    • Improved creep resistance and load-bearing capability
    • Suitable for precision machined parts requiring dimensional stability

PCTFE Plastic Properties

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Markets Served

  • Chemical Processing
  • Aerospace
  • Cryogenics
  • Oil & Gas
  • Pharmaceutical
  • Industrial Equipment

Typical Products and Applications

Products
  • Semi-finished forms: Rods & Sheets
  • Precision machined components
  • Seals, gaskets, and valve parts
  • Cryogenic components
Applications
  • Valve seats and seals
  • Pumps and compressors
  • LNG and cryogenic systems
  • Chemical handling components

Limitations of PCTFE

  • Lower maximum service temperature compared to PTFE and PEEK
  • Higher material cost than standard engineering plastics

PCTFE vs Other Materials

  • PCTFE vs PTFE
    • PCTFE provides significantly lower moisture absorption and better dimensional stability, while PTFE offers lower friction and broader temperature capability.
  • PCTFE vs PEEK
    • PEEK delivers higher mechanical strength and temperature resistance, whereas PCTFE excels in chemical resistance, barrier properties, and low permeability.
  • PCTFE vs Metal
    • PCTFE eliminates corrosion and reduces weight while offering reliable sealing and barrier performance, though it cannot replace metals in high-load structural applications.

When Should You Choose PCTFE?

PCTFE is typically selected when:

  • Low moisture absorption and gas permeability are critical
  • Tight dimensional tolerances must be maintained
  • Chemical exposure is present alongside pressure or cryogenic conditions
  • Metal corrosion or contamination must be avoided
  • Long-term stability and reliability are required
  • PCTFE may not be the best choice for high-temperature, high-friction, or heavily loaded applications

Frequently Asked Questions About PCTFE

Is PCTFE suitable for cryogenic applications?

Yes. PCTFE maintains toughness and dimensional stability at extremely low temperatures, making it well suited for cryogenic sealing and containment.

How does PCTFE compare to PTFE in moisture resistance?

PCTFE has significantly lower moisture absorption and permeability than PTFE, making it preferable for precision and barrier applications.

Is PCTFE chemically resistant?

Yes. PCTFE resists a wide range of chemicals, including acids, bases, fuels, and solvents, though compatibility should always be verified for specific media.